Ising-type Magnetic Anisotropy and Slow Relaxation of the Magnetization in Four-Coordinate Amido-Pyridine FeII Complexes
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چکیده
منابع مشابه
Slow magnetic relaxation in mononuclear seven-coordinate cobalt(II) complexes with easy plane anisotropy.
Two mononuclear seven-coordinate cobalt(II) complexes [Co(L)3(NO3)2] (L = 4-tert-butylpyridine, 1; L = isoquinoline, 2) were prepared and structurally analyzed by single-crystal X-ray crystallography. The coordination spheres of 1 and 2 exhibit distorted pentagonal bipyramid geometry. Analysis of their direct-current magnetic data reveals the existence of easy plane anisotropy (D > 0) with a sm...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2016
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.6b01512